The action gets under way on Friday July 12 when Hearts take on Dundee United at Tynecastle in Group A, live on BT Sport.
Hibernian begin their campaign the following day against Stirling Albion at Forthbank while BT Sport will show St Mirren v Dunfermline Athletic on the Sunday.
The eight group winners and four best runners-up will be joined in the last 16 by Celtic, Rangers, Kilmarnock and Aberdeen.