The Dons have finished runners-up in each of the last four seasons while the visitors will have new manager Steven Gerrard making his Premiership debut in the dug-out.
BBC ALBA will show Sunday's Hibernian v Motherwell match, kick-off 3.00pm, in full on a delayed broadcast basis from 6.00pm that evening.
Sportscene rounds up the weekend action on BBC1 Scotland at 10.30pm on Sunday.
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